I asked some of the old timer retired engineers at Collins one time if they could tell me why they chose some of the values they chose.
Here's the theory:
They wanted as low a reactance (10 to 25 ohms, or 1/5 to 1/2 the output impedance of the transmitter circuit) as they could get at 1.8 mHz without exceeding the current and power dissipation capabilities of the then available capacitors, with the RF voltages they were allowed, while using available off-the-shelf component values.
Filament and cathode bypass for RF: The average RF voltage allowed was about 5 volts at 1.8 Mhz. A .005 uF cap has a reactance or RF resistance of 18 ohms@1.8 mHz. I = V/R = 278 mA. Pdiss = 1.4 Watts.
Screen bypass without audio modulation: Again, a reactance target of about 10-25 ohms@1.8 mHz or 18 ohms for a 0.005 uF.
Screen bypass with audio modulation or self modulation: In order not to kill higher audio frequencies, a target of 100 ohms reactance was used. A 0.001 uF has a reactance of 88.5 ohms@1.8 mHz. This value would be modified depending on the
time constant of the RC circuit which comprised the screen resistor and the RF bypass components, including tube capacitance.
For the RF plate choke, they wanted a value such that the RF choke value and the RF cap. value formed a low-pass filter looking back toward the power supply, and had a resonant frequency at least 1/10 of the lowest frequency of operation.
So for a plate choke of 425 uH and a cap of 0.005 uF, the series resonant circuit had a resonant frequency of 100 kHz.
For RF coupling in interstages I prefer the micas. For RF bypass and higher power coupling purposes, I prefer the ceramics since the ceramic material has better overall heat dissipation capability.
BTW, two 0.002 uF filament bypass caps have a reactance of 22 ohms@1.8 Mhz.
So I prefer the larger physical size 0.005 or 0.01 uF ceramics for filament bypass.
0.001 uF is fine IMO for screen bypass for plate modulated final(s).
Your 6kV ceramics should be just fine for any of the bypass functions.
Phil - AC0OB
http://www.radio-electronics.com/info/data/capacitor/ceramic-capacitor.php