The 805 and its cousin the 838 are FB modulator tubes.
Best saved and used for that purpose.
They run "zero bias" in Class B as a modulator. Not good for a SE modulator, imho. For that you want an 845 or 211 - Class A "zero bias" tubes. Chinese versions will work FB.
I think PFY is giving you good advice - 1625s or 807s are rugged and plentiful, inexpensive. A quartet of them set up for AB2 will have an output power of 200 watts, fyi. You use a slightly high plate voltage, but they don't mind in modulator service. The also work FB as RF tubes. The ARC-5 ran two of them... W2JBL can be heard on the air with a modified ARC-5 on many nights here on the upper east coast sounding berry gud.
The cathode modulated idea is not half bad here either... because the voltages are fairly low (imho).
I think there are two ways to build up something - assuming you want to build up something and not just buy a DX-100, Apache or Johnson rig (for example). First decide on the power level and buy parts to suit. Or, alternately, second find whatever you can and fill in the blanks to suit.
The two main things are going to be IRON and Toobes, that and RF parts. That kinda dictates the direction... so as I suggested you can either build to a plan and get stuff together over time, or you can find stuff and build what it permits... it's hard to work the two methods together.
For example, an op here in upstate NY has been getting parts together for 3 years to build up a plate modulated transmitter based on a particular large tube... (building to a plan).
Otoh, you might find an RF deck or modulator at a hamfest, or online and then build to that, because you can...
As someone mentioned, 6146s are still inexpensive usually, and 807s, 1625s are also inexpensive, as are import 6550s (modulator tubes) and 6CA7s... for that matter so are 4D32s not too pricey for the time being... etc...
I'd say KISS - (keep it simple) and aim for what you can put together, and don't be in a hurry to use something just because it dropped into your lap, unless you end up finding the "rest" of the things needed without going crazy... sometimes it makes sense to resell things that are "desireable" for things that you can really make use of...
Now, if you had a few boxes of NOS 805s... more options open up. But one? Not so sure you want to go ahead and do much with one.
Ymmv.
_-_-WBear2GCR